姓 名:李法宝
出生年月:1978年6月
职务职称:副教授,硕士生导师
专业方向:有机化学
办公电话:02750865342
Email:lfb0615@hubu.edu.cn
研究领域与兴趣:
富勒烯化学、过渡金属催化有机新反应、有机功能光电材料合成与应用
迄今为止,已在国内外重要期刊Organic Letters, The Journal of Organic Chemistry, RSC Advances, Organic & Biomolecular Chemistry, New Journal of Chemistry等上发表SCI权威论文37篇,其中17篇论文发表在有机著名期刊Organic Letters, The Journal of Organic Chemistry上。此外,在著名百科全书Kirk-Othmer Encyclopedia of Chemical Technology及Encyclopedia of Physical Organic Chemistry上撰写富勒烯专章各一部。期刊影响因子总和累计达到140左右。
教育与研究经历:
2007.06–2010.06 在中国科学技术大学博士后流动站工作,2002.09–2007.06在中国科学技术大学有机化学专业硕博连读,获理学博士学位;1998.09–2002.07在曲阜师范大学化学专业学习,获理学学士学位;2010年7月加入bet365足球外围网站。现为湖北大学有机功能分子合成与应用教育部重点实验室研究人员。
教学情况:
承担本科生《有机化学》、《有机化学实验》等课程教学及辅导工作
承担项目与课题:
1. 主持国家自然科学基金青年项目:新型富勒烯碳杂化合物的合成及其衍生化研究 (21102041)
2. 主持湖北省教育厅科学技术研究计划重点项目:新型富勒烯反应的开发及其在光电材料合成中的应用研究(D20161007)
3. 主持湖北省自然科学基金面上项目:新型富勒烯-卟啉光电材料研究(2014CFB550)
4. 主持湖北省教育厅科学技术研究计划优秀中青年人才项目:新型含氮/氧富勒烯化合物的合成研究(Q20120113)
5. 主持有机功能分子合成与应用教育部重点实验室(湖北大学)开放基金:中性双膦铜(I)配合物电致发光材料的制备与应用(2016-KL-013)
6. 主持有机功能分子合成与应用教育部重点实验室(湖北大学)开放基金:基于氮丙啶富勒烯新反应的开发(2013-KL-010)
7. 主持湖北大学自然科学基金:新型富勒烯碳杂化合物的合成及其衍生化研究(2010)
8. 指导湖北省高等学校2013年省级大学生创新创业训练计划:新型富勒烯碳杂化合物的合成与表征(201310512011)(指导老师)
9. 指导湖北省高等学校2016年省级大学生创新创业训练计划:具有生物相容性的抗HIV病毒活性C60Cl6衍生物的合成与表征(201610512054)(指导老师)
获奖与荣誉:
1. 中国科学院院长优秀奖(2007)
2. 中国科学院王宽诚博士后工作奖(2007)
3. 湖北大学“青年突击手”(2013)
4. 指导本科论文获湖北省第八届大学生化学(化工)学术创新成果二等奖(2015)
5. 湖北大学优秀班主任(2016)
代表性成果:
1. Fa-Bao Li and Guan-Wu Wang,* “Function Oriented Molecular Design: Fullerenes and Related Carbon Materials”, in Encyclopedia of Physical Organic Chemistry, Zerong Wang, Ed., John Wiley & Sons Inc., Hoboken, Volume 3, Chapter 9, 2017, 1-75. Online ISBN: 9781118470459.(Invited Book Chapter)
2. Jun Wu, Chun-Xiang Liu, Hui-Juan Wang, Fa-Bao Li,* Ji-Long Shi, Li Liu, Jia-Xing Li,* Chao-Yang Liu,* and Yong-Shun Huang, “Cu(OAc)2-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines”, J. Org. Chem. 2016, 81, 9296-9307.
3. Ji-Long Shi, Xiao-Feng Zhang, Hui-Juan Wang, Fa-Bao Li,* Xin-Xin Zhong, Chun-Xiang Liu, Li Liu,* Chao-Yang Liu,* Hai-Mei Qin,*and Yong-Shun Huang “A Protocol for the Preparation of 2,5-Diaryl Fulleropyrrolidines: Thermal Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines”, J. Org. Chem. 2016, 81,7662-7674.(Highlighted as Hot article in August 2016)
4. Ji-Long Shi, Fa-Bao Li,* Xiao-Feng Zhang, Jun Wu, Hong-Yu Zhang, Jie Peng, Chun-Xiang Liu, Li Liu,* Ping Wu, and Jia-Xing Li “Synthesis and Functionalization of Symmetrical 2,5-Diaryl Fulleropyrrolidines: Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Arylmethanamines”,J. Org. Chem. 2016, 81,1769-1777.(Highlighted as Hot article in February 2016)
5. Hong-Yu Zhang, Hui-Juan Wang, Fa-Bao Li,* Chun-Xiang Liu, Xiao-Feng Zhang, Li Liu,* and Chao-Yang Liu* “Facile Access to 2,5-Diaryl Fulleropyrrolidines: Magnesium Perchlorate-Mediated Reaction of [60]Fullerene with Arylmethylamines and Arylaldehydes” RSC Adv. 2016, 6, 79095-79105.
6. Xiao-Feng Zhang, Fa-Bao Li,* Ji-Long Shi, Jun Wu, and Li Liu,* “Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Primary Amides for the Synthesis of Fullerooxazoles” New J. Chem. 2016, 40, 1626-1632. (Abstracted by Cheminform 2016, 15-131)
7. Tong–Xin Liu, Fa–Bao Li, Dian-Bing Zhou, and Guan–Wu Wang* “Ferric Perchlorate-Promoted Reaction of [60]Fullerene with N-Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines”, J. Org. Chem. 2015, 80, 11986-11992.
8. Xiao-Feng Zhang, Fa-Bao Li,* Jun Wu, Ji-Long Shi, Zhan Liu, and Li Liu*, “Synthesis of Fullerene-Fused Dioxanes/Dioxepanes: Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Diols” J. Org. Chem.2015, 80, 6037-6043. (Highlighted by X-MOL: http://www.x-mol.com/news/655)
9. Jun Wu, Fa-Bao Li,* Xiao-Feng Zhang, Ji-Long Shi, and Li Liu,* “TsOH-Mediated Reaction of Aziridinofullerene with Diols for the Preparation of Fullerene-Fused Dioxygenated Ring Compounds” RSC Adv. 2015, 5, 30549-30554.
10. Fa-Bao Li,* Ye-Fei Zhu, Xiao-Feng Zhang, Ji-Long Shi, Jun Wu, Liu Chen, Xiao-Xue Liang, and Li Liu,* “Synthesis of Oxazolidinofullerenes and Thiazolidinofullerenes: Novel Reaction [60]Fullerene with Isocyanates and Isothiocyanates Promoted by Ferric Perchlorate”, RSC Adv. 2014, 4, 48085-48094. (Abstracted by Cheminform 2015, 06-115)
11. Hai-Tao Yang,* Meng-Lei Xing, Ye-Fei Zhu, Xiao-Qiang Sun, Jiang Cheng, Chun-Bao Miao, and Fa-Bao Li,* “BF3·Et2O-Catalyzed Formal [3+2] Reaction of Aziridinofullerenes with Carbonyl Compounds”, J. Org. Chem. 2014, 79, 1487–1492. (Abstracted by Cheminform 2014, 29-152)
12. Xun You, Fa–Bao Li, and Guan–Wu Wang,* “Synthesis of Ortho Acid Ester-Type 1,3-Dioxolanofullerenes: Radical Reaction of [60]Fullerene with Halocarboxylic Acids Promoted by Lead(IV) Acetate” J. Org. Chem. 2014, 79, 11155-11160.
13. Fa-Bao Li and Guan-Wu Wang,* “Fullerenes”, in Kirk-Othmer Encyclopedia of Chemical Technology, Arza Seidel, Ed., John Wiley & Sons Inc., Hoboken, 2013, pp. 1-89. Online ISBN: 9780471238966. (Invited Book Chapter)
14. Fa–Bao Li, Xun You, Tong–Xin Liu, and Guan–Wu Wang* “Fullerenyl Boronic Esters: Ferric Perchlorate–Mediated Synthesis and Functionalization”, Org. Lett. 2012, 14, 1800–1803.
15. Fa–Bao Li, Xun You, and Guan–Wu Wang* “Ferric Perchlorate–Mediated Synthesis of 1,2–Fullerenols C60(OCOR)(OH)”, J. Org. Chem. 2012, 77, 6643–6647.
16. Tong–Xin Liu, Fa–Bao Li,and Guan–Wu Wang* “Synthesis of [60]Fullerene–Fused Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by Aluminum Chloride”, Org. Lett. 2011,13, 6130–6133.
17. Fa–Bao Li, Xun You, and Guan–Wu Wang* “Synthesis of Disubstituted [60]Fullerene–Fused Lactones: Ferric Perchlorate–Promoted Reaction of [60]Fullerene with Malonate Esters”, Org. Lett. 2010, 12, 4896–4899. (Highlighted by Synfacts2011, 1, 0038)
18. Fa–Bao Li, Tong–Xin Liu, Xun You, and Guan–Wu Wang* “A Facile Access to [60]Fullerene–Fused 1,3–Dioxolanes: Reaction of [60]Fullerene with Aldehydes/Ketones Promoted by Ferric Perchlorate”, Org. Lett. 2010,12, 3258–3261.
19. Fa–Bao Li, Tong–Xin Liu, Yong–Shun Huang, and Guan–Wu Wang* “Synthesis of Fullerene–Fused Lactones and Fullerenyl Esters: Radical Reaction of [60]Fullerene with Carboxylic Acids Promoted by Manganese(III) Acetate and Lead(IV) Acetate”, J. Org. Chem. 2009,74, 7743–7749.
20. Fa–Bao Li, Tong–Xin Liu, and Guan–Wu Wang* “Synthesis of Fullerooxazoles: Novel Reactions of [60]Fullerene with Nitriles Promoted by Ferric Perchlorate”, J. Org. Chem. 2008,73, 6417–6420. (Abstracted by Cheminform 2008, 14-272)
21. Guan–Wu Wang,* Fa–Bao Li,and Yu Xu “Novel Functionalizations of [60]Fullerene–Fused Lactones”,J. Org. Chem. 2007, 72, 4774–4778. (Abstracted by Cheminform 2007, 43-098)
22. Guan–Wu Wang,* Fa–Bao Li, Zhong–Xiu Chen, Ping Wu, Bin Cheng, and Yu Xu “Synthesis of [60]Fullerene Acetals and Ketals: Reaction of [60]Fullerene with Aldehydes/Ketones and Alkoxides”, J. Org. Chem. 2007, 72, 4779–4783. (Abstracted by Cheminform 2007, 43-099)
23. Guan–Wu Wang,* Fa–Bao Li, and Ting–Hu Zhang “[60]Fullerene–Fused Lactones: Manganese(III) Acetate–Mediated Synthesis and Novel Reductive Ring Opening”, Org. Lett. 2006, 8, 1355–1358. (Abstracted by Cheminform 2006, 33-120)